study of the inhibition of cooling water corrosion.

  • 0.92 MB
  • English
University of Salford , Salford
ID Numbers
Open LibraryOL20309268M

Also, the work was extended to study the corrosion inhibition effect of the selected compounds on carbon steel surface in contact with cooling water using both potentiodynamic polarization and electrochemical impedance spectroscopy techniques.

It was found that the selected compound acts as a good scale and corrosion : Mohamed Migahed, A.M. Al-Sabagh, R. Habib Habib. The applications of corrosion inhibition are wide ranging. Examples given in this book include: oil and gas wells, petrochemical plants, steel reinforced cement, water cooling systems, and many more.

The final chapters discuss economic and environmental considerations which are now of prime importance. The best way to prevent crevice corrosion is to prevent crevices. From a cooling water standpoint, this requires the prevention of deposits on the metal surface. Deposits may be formed by suspended solids (e.g., silt, silica) or by precipitating species, such as calcium salts.

Intergranular Corrosion. Intergranular corrosion is localized attack. The corrosion inhibition rate η was calculated by the Formula (2). % X X X % 0 0 1 u K (2) In this formula, X 0 and X 1 are the weight loss values of carbon steel after 72 hours being immersed in the simulated cooling water without and with corrosion and scale inhibitors.

The electrochemicalAuthor: Defang Zeng, Huan Yan. @article{osti_, title = {Sodium molybdate corrosion inhibitor for boiler feedwater systems}, author = {Robitaille, D.R.}, abstractNote = {Molybdate-containing corrosion inhibotors are becoming more attractive in an increasing number of commercial applications.

Sodium molybdate inhibits corrosion of low carbon steel, copper and brass in recirculating cooling. A study of the carbon steel/cooling water interface was carried out using electrochemical impedance spectroscopy (EIS). EIS spectra reveal that a layer of corrosion and scale products forms naturally and evolves with the immersion time modifying the carbon steel/cooling water interface and giving rise to corrosion and scale by: Corrosion inhibitors are chemical products which, when added to water or to any other process fluid, slow down the rate of corrosion.

study of the inhibition of cooling water corrosion. book They are normally classified as: anodic, cathodic, film-forming and oxygen-absorbing agents depending on their mode of action.

The effectiveness of most corrosion inhibitors is significantly affected by the water. The polymer–polymer complexes [(PMAAN/PAAmM)], composed of polymethacrylic acid (PMAAN) and polyacrylamide (PAAmM) were investigated as inhibitors for corrosion of mild steel in cooling water systems.

The inhibition abilities of (PMAAN/PAAmM) against corrosion and scale deposition were evaluated by corrosion tests and physicochemical by: 3. Abstract. Three types of corrosion inhibitors consisting of sodium diphosphate (Na 2 H 2 P 2 O 7), sodium benzoate (NaC 7 H 5 O 2), and sodium tetraborate (Na 2 B 4 O 7) were evaluated to analyze their effectiveness to inhibit the aluminum alloy (UNS A) against corrosion, in water-ethylene glycol (C 2 H 6 O 2) iodynamic polarization tests were carried Cited by: 2.

Corrosion Case, Corrosion Test The presentation of Wayne D. Niemeyer (2nd case starting from ) has demonstrated the importance of understanding of process and production chemistry for the corrosion root cause analysis(RCA).

Corrosion inhibition of mild steel by sodium nitrite in simulated cooling water (SCW) containing chloride ion was investigated. Electrochemical techniques such as corrosion potential (Ecorr.

The present work focuses on the study of the combined effects of citric acid concentration (as a green corrosion inhibitor) and fluid flow on corrosion of steel in simulated cooling water.

Both of the formulations are designed to provide excellent corrosion inhibition and deposit control in comfort cooling systems, with a cooling water reserve of about 75– ppm. Formulation A will yield ~ ppm Mo, and the operating pH is around –, while Formulation B will yield ~ ppm Mo with the operation pH of – (Table Author: Yun Chen, Wenzhong Yang.

This book documents the proceedings of the Industrial Water Treatment: Trends, Challenges, and Solutions symposium, which was sponsored by NACE International Committee STG 11 and held in Vancouver, British Columbia, Canada, from.

Corrosion is a natural process driven by energy consideration. Inhibition is a preventive measure against corrosive attack on metallic materials. Corrosion inhibitors have been frequently studied, since they offer simple solution for protection of metals against corrosion in aqueous environment.

Mineral acids like hydrochloric and sulfuric acids are most widely used in pickling baths to. @article{osti_, title = {Inhibition by phosphates of mild steel and cast iron in cooling water}, author = {Starostina, M.

and Smorodin, A. and Gal-Or, L.}, abstractNote = {The effectiveness of corrosion inhibition of mild steel and cast iron in cooling water systems by phosphonates has been studied by electrochemical techniques and weight-loss tests.

THIS IS A DOWNLOADABLE E-BOOK: Open this e-book with an e-book reader. This book documents the proceedings of the Industrial Water Treatment: Trends, Challenges, and Solutions symposium, which was sponsored by NACE International Committee STG 11 and held in Vancouver, British Columbia, Canada, from March 6 to 10,as part of Corrosion Keywords: corrosion in cooling tower, carbon steel corrosion, corrosion inhibitor of cooling tower.

Introduction The term “corrosion” (in a cooling water system) is defined as the electrochemical deterioration of a metal that is in contact with cooling water.

Corrosion occurs when an electric current flows from one part of the metal (anode). Corrosion and scaling are the main problems in cooling water systems.

To address these problems, this paper aimed to study the inhibition efficiency of some amine derivatives for carbon steel in sea water using electrochemical techniques such as potentiodynamic polarization and electrochemical impedance spectroscopy (EIS).Cited by: Inhibition of mild steel corrosion in cooling systems by low- and non-toxic corrosion inhibitors A Thesis Submitted to the University of Manchester for the Degree of Doctor of Philosophy in the Faculty of Science and Engineering Mohamed Ali Ahmed Ali School of Materials.

Open cooling systems Mild steel corrosion control, all organic and zinc based programs, effective scale control in moderate hardness waters • Multifunctional deposit control in a single additive.

• All organic corrosion inhibitor allows metal-free formulations. • Effective in a wide range of waters including soft and hard Size: 2MB. Chapter I Introduction to corrosion and corrosion inhibitors 5 Fig.

Stainless steel sheet before and after pickling. Cooling and heating water circulation system can present several problems.

Details study of the inhibition of cooling water corrosion. PDF

Formation of salt deposits and fouling by micro-organisms can appear when water is used as thermal fluid (Fig. An investigation was conducted to improve the corrosion inhibition efficiency of molybdate-based inhibitors for mild steel which is the main construction material of cooling water systems, using nitroethane as an organic compound beside zinc.

In this study a new molybdate-based inhibitor was introduced with the composition of 60 ppm molybdate, 20&#x;ppm nitrite, Cited by: 1. TREATMENT AND CORROSION CONTROL OF COOLING WATER Page 5 The main chemical factors which influence the tendency of cooling water to corrode are mineral salt content, pH value and dissolved gases, notably oxygen and carbon dioxide.

Gases including sulphur dioxide and ammonia, chlorine etc., may contaminate the system being eitherFile Size: KB. Cooling water systems are integral part of most of the industries and their performance is seriously affected by corrosion of materials and scale deposits.

Use of inhibitors in controlling corrosion/scales in cooling water systems is an established technology.

Download study of the inhibition of cooling water corrosion. PDF

COOLING WATER PROBLEMS AND SOLUTIONS Water is used in cooling systems as a heat transfer medium and frequently also as the final point to reject heat into the atmosphere by evaporating inside cooling towers. Depending on the quality of available fresh water supply, waterside problems develop in cooling water systems from: • Scaling • Corrosion.

Cooling Towers Case Study: High Phosphate Levels By Alicia Kenney added to water by the city for the same reason that we add it: corrosion inhibition. If the city increased their phosphate feed and city water was the source of the tower makeup, it may result inFile Size: KB.

The anatomy of tubercles: A corrosion study in a fresh water estuary Dedicated to Professor Dr. Wolfgang Sand on the occasion of his 60th birthday R. Ray, J. Lee, B. Little* and T. Gerke The structure and mineralogy of corrosion products formed on carbon steel coupons exposed in Duluth Superior Harbor (DSH, USA), were investigated andCited by: The incumbent water treatment provider was treating their 3 cell, 25, gpm recirculation rate cooling system with ozone as the biocide along with an organic based scale and corrosion inhibitor.

The client was getting higher than desired corrosion rates of 8 mpy on mild steel and wanted lower corrosion rates.


Tolyltriazole (TTA) has been identified as an effective copper corrosion inhibitor in cooling systems using treated municipal effluent as makeup water. Significant removal of TTA from solution has been reported in previous studies in the presence of free chlorine and copper metal.

Hence, for effective dosing of TTA in the cooling systems, it is important to understand Cited by: 7.1. types of cooling water systems 2. cooling tower water calculations 3. objectives of cooling water treatment 4. microbiological deposits and control 5.

Description study of the inhibition of cooling water corrosion. PDF

corrosion in cooling systems 6. developing an effective cooling water treatment program 7. cooling water system start-up .Types of Cooling Water Corrosion General Corrosion: Metal loss occurs uniformly over the entire surface.

Localized or Pitting Corrosion: Extremely localized type of corrosion resulting in pits or holes in the metal. Galvanic Corrosion: Different metals in contact in a system creating a difference in potential.